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Comments are screened for your privacy, although I'm not quite sure how that would continue to work if I post a response. If you really need confidentiality, say something, and make sure you give us a valid email address to reach you at.
I have turned email notification on. If something is time-critical (e.g., troll/spam invasion), please try to reach at least one of the other mods as well. I don't, as a rule, do LJ from work, but one of us (usually not me) is almost always close enough to a computer to do something.
We (the mod team) talk to each other, so if I don't know the answer off hand, can't field your request, or need a consensus, I will certainly let them know.
And remember ... as sunfell says, "Play nice."